ELECTROORGANIC REACTIONS ON ORGANIC ELECTRODES .15. ELECTROLYSIS USING COMPOSITE-PLATED ELECTRODES .4. POLARIZATION STUDY ON A HYDROPHOBIC NI/PTFE COMPOSITE-PLATED NICKEL ELECTRODE

被引：36

作者：

KUNUGI, Y ^{[1
]}

NONAKA, T ^{[1
]}

CHONG, YB ^{[1
]}

WATANABE, N ^{[1
]}

机构：

[1] APPL SCI RES INST,SAKYO KU,KYOTO 606,JAPAN

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 02期

关键词：

HYDROPHOBIC ELECTRODE; OXIDATION AND REDUCTION OF ORGANIC COMPOUNDS;

D O I：

10.1016/0013-4686(92)85023-E

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

It was found that a hydrophobic Ni/poly(tetrafluoroethylene) [PTFE] composite-plated nickel electrode has lower oxygen and hydrogen overvoltages in a wide range of current density than an unplated nickel one. When an electrooxidizable organic compound (isopropyl alcohol) was added to an aqueous alkaline anolyte, a current-potential curve for its oxidation on the Ni/PTFE anode shifted drastically to a cathodic direction from that in the background solution, while the potential shift on the unplated anode was much less. On the other hand, in the reduction of benzaldehyde on the Ni/PTFE cathode the potential shift to an anodic direction was observed. A preliminary investigation about the overvoltage increase and the potential shift was made.

引用

页码：353 / 355

页数：3

共 8 条

[1]

DEAN JA, 1985, LANGES HDB CHEM, P6

[2]

FUZISHIMA A, 1984, DENKI KAGAKU SOKUTEI, P95

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