THE PREPARATION, STABILITY AND REACTIVITY OF PERFLUOROBENZYL-CADMIUM AND PERFLUOROBENZYL-COPPER REAGENTS

被引：6

作者：

BURTON, DJ

YANG, ZY

PLATONOV, V

机构：

[1] Department of Chemistry, University of Iowa, Iowa City

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1994年 / 66卷 / 01期

关键词：

D O I：

10.1016/0022-1139(93)02919-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluorobenzyl bromide reacts readily with acid-washed cadmium powder in DMF at room temperature to give the F-benzylcadmium reagent. Metathesis of the F-benzylcadmium reagent with Cu(I)Br at -40-degrees-C to -35-degrees-C in DMF affords the F-benzylcopper reagent. The formation of the F-benzylcadmium and -copper reagents was confirmed by F-19 NMR spectral analysis of the reaction mixture and chemical transformations.

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页码：23 / 24

页数：2

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