CONJUGATED MACROCYCLES RELATED TO THE PORPHYRINS .3. ACID-CATALYZED CONDENSATIONS OF THIOPHENECARBOXALDEHYDES WITH A DIPYRRYLMETHANE

被引：9

作者：

ARMIGER, YLST

LASH, TD

机构：

[1] Department of Chemistry, Illinois State University, Normal, Illinois

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1992年 / 29卷 / 02期

关键词：

D O I：

10.1002/jhet.5570290240

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

MacDonald condensation of a dipyrrylmethanedicarboxylic acid 3b with 2,2'-dithienylmethane-5,5'-dicarboxaldehyde (2b) failed to give the expected dithiophene porphyrin analog lb. However, oxidation of the reaction mixtures with DDQ gave trace amounts of porphyrin-like materials. Model studies indicate that these fractions are meso-dithienylporphyrins. The synthesis of three related alpha,gamma-disubstituted porphyrins is described.

引用

页码：523 / 527

页数：5