PREPARATION OF MULTICATION ALPHA-SIALON CONTAINING STRONTIUM

被引:64
作者
HWANG, CJ [1 ]
SUSNITZKY, DW [1 ]
BEAMAN, DR [1 ]
机构
[1] DOW CHEM CO USA,ANALYT SCI LAB,MIDLAND,MI 48667
关键词
D O I
10.1111/j.1151-2916.1995.tb08219.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The possibility of having Sr as an interstitial metal cation in alpha-SiAlON has been investigated in two systems: a single-cation system (Si3N4-SrO-AlN) and a multication system (Si3N4-(Y2O3/SrO/CaO)-AlN). It was found that Sr alone does not form alpha-SiAlON and that Sr could only be accommodated in alpha-SiAlON in conjunction with Y and Ca. The Sr content of alpha-SiAlON increased as the total content of (Y + Ca) increased and appeared to reach a limit at 0.5 at.%, or 0.15 atom per alpha-SiAlON. Unexpectedly, some of the alpha-SiAlON that contained (Sr + Y + Ca) was present as laths or fibers with the c-axis perpendicular to the hot-press direction.
引用
收藏
页码:588 / 592
页数:5
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