COMPLEX HALIDES OF THE TRANSITION-METALS .27. REACTIONS OF NITRIC-OXIDE WITH MOLYBDENUM(II) DIMERS CONTAINING METAL-METAL QUADRUPLE BONDS - NEW ROUTE TO MONOMERIC DINITROSYL DERIVATIVES OF MOLYBDENUM

被引：22

作者：

NIMRY, T ^{[1
]}

URBANCIC, MA ^{[1
]}

WALTON, RA ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 03期

关键词：

D O I：

10.1021/ic50193a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nitric oxide reacts with the metal-metal bonded dimers Mo2X4L4, where X=Cl or Br and L=PEtPh2, PEt3, or P-n-Bu3, and Mo2X4(LL)2, where X=Cl or NCS and LL=l,2-bis(diphenylphosphino)ethane (dppe) or bis(diphenylphosphino)methane (dppm) in dichloromethane to afford the dinitrosyls of molybdenum, Mo(NO)2X2L2 and Mo(NO)2X2(LL). The cleavage of the Mo-Mo quadruple bond of the starting materials is contrasted with the reaction of carbon monoxide with the rhenium(II) dimers Re2X4(PR3)4 to produce trans-Re(CO)2X2(PR3)2 and the lack of reactivity of Mo2X4(PR3)4 toward this same ligand. © 1979, American Chemical Society. All rights reserved.

引用

页码：691 / 695

页数：5

共 29 条

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