CONDUCTION-ELECTRON SPIN-RESONANCE IN LANGMUIR-BLODGETT-FILMS OF A CHARGE-TRANSFER COMPLEX

被引：16

作者：

IKEGAMI, K

KURODA, S

NAKAMURA, T

YUNOME, G

MATSUMOTO, M

HORIUCHI, S

YAMOCHI, H

SAITO, G

机构：

[1] NATL INST MAT & CHEM RES,HIGASHI KU,TSUKUBA 305,JAPAN

[2] KYOTO UNIV,FAC SCI,DEPT CHEM,SAKYO KU,KYOTO 606,JAPAN

来源：

PHYSICAL REVIEW B | 1994年 / 49卷 / 15期

关键词：

D O I：

10.1103/PhysRevB.49.10806

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electron-spin-resonance measurements were performed on the newly developed conducting Langmuir-Blodgett films consisting of a charge-transfer complex of bis(ethylenedioxy)tetrathiafulvalene (BO) and decyltetracyanoquinodimethane. The temperature-dependent spin susceptibility and linewidth clearly indicate that the major region of the films has a metallic nature. The density of states has been estimated as 3.5 states/eV per BO molecule, assuming no electron correlation. No metal-insulator transition has been detected at least down to 50 K, while an anomaly seen in the linewidth around 140 K suggests a certain kind of structural transition.

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收藏

页码：10806 / 10809

页数：4

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