PRODUCT POLARIZATION IN THE CA(1D2)+HCL-]CACL(B)+H REACTION

被引：20

作者：

GARAY, M

MENENDEZ, M

VERDASCO, E

CASTANO, J

URENA, AG

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM FIS,E-28040 MADRID,SPAIN

[2] UNIDAD LASERES & HACES MOLEC,CTR INVEST COMPLUTENSE,E-28040 MADRID,SPAIN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 22期

关键词：

D O I：

10.1021/j100124a009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Ca(D-1(2)) + HCl --> CaCl(B) + H reaction has been studied under beam-gas conditions. The product polarization of the chemiluminescence emission was measured at 0.1 eV of collision energy, indicating a strong product rotational momentum alignment. The reaction stereodynamics are discussed with the aid of a dynamical model for kinematically constrained reactions.

引用

页码：5836 / 5838

页数：3

共 11 条

[1] ANGULAR-MOMENTUM DISPOSAL AND PRODUCT ROTATIONAL ALIGNMENT IN KINEMATICALLY CONSTRAINED REACTIONS [J].