共 11 条
[11]
VERDASCO E, 1980, J CHEM PHYS, V93, P428
PRODUCT POLARIZATION IN THE CA(1D2)+HCL-]CACL(B)+H REACTION
被引：20
作者：
GARAY, M
MENENDEZ, M
VERDASCO, E
CASTANO, J
URENA, AG
机构：
[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM FIS,E-28040 MADRID,SPAIN
[2] UNIDAD LASERES & HACES MOLEC,CTR INVEST COMPLUTENSE,E-28040 MADRID,SPAIN
关键词：
D O I：
10.1021/j100124a009
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ;
081704 ;
摘要：
The Ca(D-1(2)) + HCl --> CaCl(B) + H reaction has been studied under beam-gas conditions. The product polarization of the chemiluminescence emission was measured at 0.1 eV of collision energy, indicating a strong product rotational momentum alignment. The reaction stereodynamics are discussed with the aid of a dynamical model for kinematically constrained reactions.
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页码：5836 / 5838
页数：3
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