HYDRODYNAMIC SHIELDING INDUCED STABILITY OF ZIPPING MACROMOLECULES IN ELONGATIONAL FLOWS

被引：16

作者：

AGARWAL, US ^{[1
]}

MASHELKAR, RA ^{[1
]}

机构：

[1] NATL CHEM LAB, Pune 411008, INDIA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 08期

关键词：

D O I：

10.1063/1.467116

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Enhanced shear stability of associating polymers during drag reduction observed recently has been attributed to the breakage of reversible associations (e.g., hydrogen bonds) in preference to covalent bonds in the polymer backbone. A simple mechanistic analysis of a perfectly ''zipped'' assembly of fully extended bead rod chain model of two macromolecules in steady elongational flow is presented. It explains the enhanced stability as a result of (i) distribution (near the vulnerable chain center) of the drag tension into the two parallel ''zipped'' chains, and (ii) reduction of the drag force due to the enhanced hydrodynamic shielding. Some guidelines for optimum design of shear stable and effective drag reducing macromolecules have been deduced.

引用

页码：6055 / 6061

页数：7

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