PREDICTIONS OF THE MISCIBILITY BEHAVIOR OF COPOLYMER BLENDS INVOLVING THE MONOMERS N-PHENYLITACONIMIDE, METHYL-METHACRYLATE, STYRENE AND ACRYLONITRILE

被引：39

作者：

COWIE, JMG ^{[1
]}

REID, VMC ^{[1
]}

MCEWEN, IJ ^{[1
]}

机构：

[1] UNIV STIRLING,DEPT CHEM,STIRLING FK9 4LA,SCOTLAND

来源：

POLYMER | 1990年 / 31卷 / 05期

关键词：

copolymer composition; copolymers; miscibility; segmental interaction;

D O I：

10.1016/0032-3861(90)90054-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Using the six segmental interaction parameters that characterize the pair interactions between the monomer units N-phenylitaconimide, methyl methacrylate, styrene and acrylonitrile, the theoretical miscibility ranges of several copolymer-copolymer combinations have been calculated. Comparison with the experimental phase behaviour has shown that acceptable predictions can be obtained, but also suggests that the adoption of uniquely valued interaction parameters may be inadequate to describe all situations, and the effects of polymer chain environment may have to be considered. © 1990.

引用

页码：905 / 908

页数：4