PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC ALKYLATION USING DIMETHYL MALONATE AND ITS DERIVATIVES AS NUCLEOPHILE

被引：84

作者：

YAMAGUCHI, M

SHIMA, T

YAMAGISHI, T

HIDA, M

机构：

[1] Department of Industrial Chemistry, Faculty of Technology, Tokyo Metropolitan University, Tokyo, 192-03, Minami-osawa, Hachi-oji

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(00)86120-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate with sodium salt of dimethyl malonate and its derivatives has been successfully carried out in the presence of optically active diphosphine, such as (S)-BINAP. High enantioselectivity of up to 90% ee was obtained with dimethyl malonate.

引用

页码：663 / 666

页数：4

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