PHOSPHORUS-COMPOUNDS .77. THE FIRST CARBON-PHOSPHORUS-ALUMINUM CAGE COMPOUNDS - CYCLOOLIGOMERIZATION OF PHOSPHAALKYNES WITH TRIALKYLALUMINUM COMPOUNDS

被引：11

作者：

BREIT, B

HOFFMANN, A

BERGSTRASSER, U

RICARD, L

MATHEY, F

REGITZ, M

机构：

[1] UNIV KAISERSLAUTERN, FACHBEREICH CHEM, D-67663 KAISERSLAUTERN, GERMANY

[2] ECOLE POLYTECH, DEPT CHIM, DCFG FRANCE, F-91128 PALAISEAU, FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199414911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Depending on the solvent, two completely different products are obtained from the title reaction: the cage compound 1 (91%) is formed from 2 and AlEt3 (mol ratio 3:2) in n‐hexane, whereas the polycycle 3 (74%) results from 2 and AlEt3 (mol ratio 4:1) in diethyl ether. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1491 / 1493

页数：3

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