DEOXOPHYLLOERYTHROETIOPORPHYRIN

被引：61

作者：

BAKER, EW

CORWIN, AH

KLESPER, E

WEI, PE

机构：

[1] Mellon Institute, Carnegie-Mellon University, Pittsburgh

[2] Department of Chemistry, Johns Hopkins University, Baltimore

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 08期

关键词：

D O I：

10.1021/jo01272a026

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method of preparation of deoxophylloerythroetioporphyrin using the chlorophyll derivative, pheophytin, as the starting material has been worked out. In the procedure pheophytin is first converted into pyropheophorbide which is further degraded to deoxophylloerythrin in a single composite reaction based on the Wolff-Kishner reduction. Deoxophylloerythrin is then decarboxylated to yield deoxophylloerythroetioporphyrin by a sevenstep reaction which includes Curtins rearrangement, Hofmann degradation, and catalytic hydrogenation. © 1968, American Chemical Society. All rights reserved.

引用

页码：3144 / &

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