FULLY INORGANIC (CARBON-FREE) FULLERENES - THE BORON-NITROGEN CASE

被引：42

作者：

SILAGHIDUMITRESCU, I

HAIDUC, I

SOWERBY, DB

机构：

[1] UNIV BABES BOLYAI,FAC CHIM,R-3400 CLUJ NAPOCA,ROMANIA

[2] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 17期

关键词：

D O I：

10.1021/ic00069a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Closed cages containing only boron and nitrogen atoms can be constructed from four-membered B2N2 rings and six-membered B3N3 rings. The ring-spiral algorithm applied to such cages and Huckel molecular orbital calculations suggest that a series of stable ''accordion-shaped'' cages, with the general formula B12+3nN12+3n can exist. In addition, on the basis of different principles, a B22N22 Cage seems also possible.

引用

页码：3755 / 3758

页数：4

共 30 条

[1] ELECTRONIC STRUCTURE OF DIMERIC AMINOBORANE, (NH2BH2)2
ARMSTRON.DR
PERKINS, PG
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (16): : 2748 - &
[2] MOLECULAR ORBITAL CALCULATIONS FOR CONJUGATED MOLECULES CONTAINING BORON AND NITROGEN
BAIRD, NC
WHITEHEAD, MA
[J]. CANADIAN JOURNAL OF CHEMISTRY-BACK YEAR, 1967, 45 (18): : 2059 - +
[3] STABILITY AND STRUCTURE OF C12B24N24 - A HYBRID ANALOG OF BUCKMINSTERFULLERENE
BOWSER, JR
JELSKI, DA
GEORGE, TF
[J]. INORGANIC CHEMISTRY, 1992, 31 (02) : 154 - 156
[4] BRAUN T, 1992, ANGEW CHEM, V104, P602
[5] BUENKER RJ, 1969, J AM CHEM SOC, V93, P4342
[6] DIETRICH F, 1991, ANGEW CHEM INT EDIT, V30, P678
[7] MAGIC NUMBERS AND STABLE STRUCTURES FOR FULLERENES, FULLERIDES AND FULLERENIUM IONS
FOWLER, PW
MANOLOPOULOS, DE
[J]. NATURE, 1992, 355 (6359) : 428 - 430
[8] METALLO-CARBOHEDRENES [M8C12+ (M = V, ZR, HF, AND TI)] - A CLASS OF STABLE MOLECULAR CLUSTER IONS
GUO, BC
WEI, S
PURNELL, J
BUZZA, S
CASTLEMAN, AW
[J]. SCIENCE, 1992, 256 (5056) : 515 - 516
[9] TI8C12+-METALLO-CARBOHEDRENES - A NEW CLASS OF MOLECULAR CLUSTERS
GUO, BC
KERNS, KP
CASTLEMAN, AW
[J]. SCIENCE, 1992, 255 (5050) : 1411 - 1413
[10] HAIDUC I, 1970, CHEM INORGANIC RING, V1, P240

← 1 2 3 →