FULLY INORGANIC (CARBON-FREE) FULLERENES - THE BORON-NITROGEN CASE

被引：42

作者：

SILAGHIDUMITRESCU, I

HAIDUC, I

SOWERBY, DB

机构：

[1] UNIV BABES BOLYAI,FAC CHIM,R-3400 CLUJ NAPOCA,ROMANIA

[2] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 17期

关键词：

D O I：

10.1021/ic00069a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Closed cages containing only boron and nitrogen atoms can be constructed from four-membered B2N2 rings and six-membered B3N3 rings. The ring-spiral algorithm applied to such cages and Huckel molecular orbital calculations suggest that a series of stable ''accordion-shaped'' cages, with the general formula B12+3nN12+3n can exist. In addition, on the basis of different principles, a B22N22 Cage seems also possible.

引用

页码：3755 / 3758

页数：4

共 30 条

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