INTERCALATION OF THE COPPER(II) PHTHALOCYANINE TETRASULFONATE ANION (CUPCTS(4-)) INTO BASIC COPPER(II) SALTS

被引：15

作者：

HAYASHI, H ^{[1
]}

HUDSON, MJ ^{[1
]}

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 05期

关键词：

D O I：

10.1039/jm9950500781

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Intercalation of the copper(II)) phthalocyanine tetrasulfonate (CuPcTs(4-)) anion by exchange into basic copper salts with NO3- or CH3CO2- as the interlayer anion has been studied. No intercalation took place with the basic copper(II) nitrate Cu-2(OH)(3)NO3 (BCN). In contrast, CuPcTs(4-) anions were readily intercalated into basic copper(tl) acetate Cu-2(OH)(3)CH3CO2 (BCA) such that the anions were orientated with the molecular planes approximately perpendicular to the Cu-2(OH)(3)(+) layers of the host material. This difference in the intercalation properties between BCN and BCA may be mainly related to the difference between their gallery heights (3.4 and 5.8 Angstrom, respectively) and the intersectional diameter (5.5 Angstrom) of the CuPcTs(4-) anion.

引用

页码：781 / 783

页数：3

共 10 条

[1] INCORPORATION OF PHTHALOCYANINES BY CATIONIC AND ANIONIC CLAYS VIA ION-EXCHANGE AND DIRECT SYNTHESIS [J].