Alternative processes for the production of styrene

被引：324

作者：

Cavani, F

Trifiro, F

机构：

[1] Dipartimento di Chimica Industriale e dei Materiali, Universitàdi Bologna, Viale Risorgimento 4

来源：

APPLIED CATALYSIS A-GENERAL | 1995年 / 133卷 / 02期

关键词：

ethylbenzene; styrene; dehydrogenation; oxidative dehydrogenation; membrane reactor;

D O I：

10.1016/0926-860X(95)00218-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This short review compares different technologies for the synthesis of styrene which are currently studied as alternatives to the industrial dehydrogenation of ethylbenzene: dehydrogenation of ethylbenzene followed by oxidation of hydrogen, catalytic and stoichiometric oxidative dehydrogenation of ethylbenzene, and dehydrogenation in membrane reactors. The advantages and drawbacks of each technology are illustrated and discussed, and the catalytic systems employed are described.

引用

页码：219 / 239

页数：21

共 50 条

[11] OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE OVER CARBONACEOUS CATALYSTS
DRAGO, RS
JURCZYK, K
[J]. APPLIED CATALYSIS A-GENERAL, 1994, 112 (02) : 117 - 124
[12] Drehman L. E., 1972, US Patent, Patent No. [3,670,044, 3670044]
[13] ECHIGOYA E, 1984, 8TH P INT C CAT, V5, P623
[14] ACTION OF ZIRCONIUM-PHOSPHATE AS A CATALYST FOR THE OXYDEHYDROGENATION OF ETHYLBENZENE TO STYRENE
EMIG, G
HOFMANN, H
[J]. JOURNAL OF CATALYSIS, 1983, 84 (01) : 15 - 26
[15] THE NATURE AND CATALYTIC INFLUENCE OF COKE FORMED ON ALUMINA - OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE
FIEDOROW, R
PRZYSTAJKO, W
SOPA, M
[J]. JOURNAL OF CATALYSIS, 1981, 68 (01) : 33 - 41
[16] FONT JJ, 1989, Patent No. 332289
[17] OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE OVER CARBON-BASED CATALYSTS
GRUNEWALD, GC
DRAGO, RS
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 58 (02): : 227 - 233
[18] STRUCTURE OF THE ACTIVE LAYER AND CATALYTIC MECHANISM OF THE V2O5/MGO CATALYSTS IN THE OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE TO STYRENE
HANUZA, J
JEZOWSKATRZEBIATOWSKA, B
OGANOWSKI, W
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1985, 29 (01): : 109 - 143
[19] Herber R. R., 1989, [No title captured], Patent No. [US 4806624, 4806624]
[20] DEHYDROGENATION OF ETHYLBENZENE OVER POTASSIUM-PROMOTED IRON-OXIDE CONTAINING CERIUM AND MOLYBDENUM OXIDES
HIRANO, T
[J]. APPLIED CATALYSIS, 1986, 28 (1-2): : 119 - 132

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