COMPUTER MODELING OF MULTISTEP CARBONIUM-ION REARRANGEMENTS - APPLICATIONS TO METHYLCYCLOPENTYL AND TERT-AMYL

被引：9

作者：

SAUNDERS, M

BUDIANSKY, SP

机构：

[1] Sterling Chemistry Laboratory, Yale University, New Haven

来源：

TETRAHEDRON | 1979年 / 35卷 / 08期

关键词：

D O I：

10.1016/S0040-4020(01)93704-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general Monte-Carlo method computer program is described which simulates carbonium ion rearrangements via 1,2-hydride shifts and protonated-cyclopropanes. Its application in examining possible overall rearrangement mechanisms in t-amyl cation is discussed. Results from an earlier version of the program for the case of methylcyclopentyl cation are also presented. © 1979.

引用

页码：929 / 932

页数：4