MOLECULAR-REORIENTATION OF CCL4 AND CS2 IN ALKANES - C-13 AND S-33 NMR RELAXATION STUDY

被引:10
作者
ANCIAN, B
TIFFON, B
DUBOIS, JE
机构
[1] Institut de Topologie et de Dynamique des Systèmes, l'Université Paris VII, associé au C.N.R.S.
关键词
D O I
10.1016/0009-2614(79)87065-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Reorientational and angular momentum correlation times τc and τJ for CCl4 and CS2 in alkanes have been derived from 13C spin-spin relaxation times of CCl4 and 33S linewidths of CS2. In contrast with neat liquids, molecular reorientation does not obey J-diffusion, but tends towards M-diffusion in large solvents. © 1979.
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页码:281 / 286
页数:6
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