REACTIONS OF BROMOTRIFLUOROMETHANE AND RELATED HALIDES .12. TRANSFORMATION OF DISULFIDES INTO PERFLUOROALKYL SULFIDES IN THE PRESENCE OF SULFOXYLATE ANION RADICAL PRECURSORS

被引：34

作者：

CLAVEL, JL

LANGLOIS, B

NANTERMET, R

TORDEUX, M

WAKSELMAN, C

机构：

[1] CNRS,CERCOA,2 RUE HENRI DUNANT,F-94320 THIAIS,FRANCE

[2] UNIV LYON 1,CHIM ORGAN LAB 3,CNRS,URA 467,F-69622 VILLEURBANNE,FRANCE

[3] RHONE POULENC RECH,CTR RECH CARRIERES,F-69192 ST FONS,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 24期

关键词：

D O I：

10.1039/p19920003371

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluoroalkyl sulfides are prepared by reaction of perfluoroalkyl halides with disulfides in the presence of sulfoxylate anion radical precursors. Aliphatic, aromatic and heteroaromatic disulfides bearing cyano, ester and amino functional groups have been employed; a variety of perhalogenoalkanes can also be employed, e.g. CF3(CF2)nI, CF3Br, CF2Br2, CF2BrCI, CFCI3 and CF2CICFCI2. The most convenient sulfoxylate anion radical precursor for this reaction is formed by a combination of sodium formate and sulfur dioxide.

引用

页码：3371 / 3375

页数：5

共 42 条

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