LIGAND-DEPENDENT PRODUCT FORMATION IN THE CONVERSION OF 1,7-OCTADIENE WITH PHENYLISOCYANATE ON NICKEL(0)

被引：10

作者：

HOBERG, H

GUHL, D

机构：

[1] Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 384卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)87082-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,7-Octadiene and phenylisocyanate react with the (Lig)Ni0-system, depending on the ligand, to give differing products. Thus with tricyclohexylphosphane the reaction is accompanied by cyclization and (2-methylenecyclohexyl)acetanilide(V) is formed. On the other hand, reaction with the weakly basic tricyclohexylphosphite gives the acyclic nona-2,8-dienecarboxanilide (VI). © 1990.

引用

页码：C43 / C46

页数：4

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