STUDY ON ROUGH-SURFACE BIAXIALLY ORIENTED POLYPROPYLENE FILM .1. FORMATION OF BETA-FORM CRYSTALS IN SHEET CAST WITH T-DIE EXTRUDER

被引:32
作者
FUJIYAMA, M [1 ]
KAWAMURA, Y [1 ]
WAKINO, T [1 ]
OKAMOTO, T [1 ]
机构
[1] TOKUYAMA SODA CO LTD,DIV ELECTR BUSINESS,PRINTED CIRCUIT PROD,FUJISAWA,KANAGAWA 252,JAPAN
关键词
CRYSTALS - Forming - PLASTICS MACHINERY - Extruders - PLASTICS SHEETS - Extrusion - POLYPROPYLENE - Extrusion;
D O I
10.1002/app.1988.070360501
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Sheets were cast by extruding polypropylenes (PP) which contained gamma -quinacridone, a beta -crystal nucleator, at levels of 0-10 ppm using a 30 mm phi extruder with a T-die at extrusion temperatures of 200-260 degree C and chill roll temperatures of 30-90 degree C. The influences of raw resin characteristics such as gamma -quinacridone content and MFI of the base PP and casting conditions such as extrusion temperature and chill roll temperature on the amount of beta -crystals formed in the sheet were studied. The amount of the beta -crystals formed was larger as the gamma -quinacridone content was higher and the extrusion temperature was lower and almost independent of the chill roll temperature.
引用
收藏
页码:985 / 993
页数:9
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