OXIDATION OF ALKANES BY DIOXYGEN CATALYZED BY PHOTOACTIVATED IRON PORPHYRINS

被引：71

作者：

MALDOTTI, A ^{[1
]}

BARTOCCI, C ^{[1
]}

AMADELLI, R ^{[1
]}

POLO, E ^{[1
]}

BATTIONI, P ^{[1
]}

MANSUY, D ^{[1
]}

机构：

[1] UNIV PARIS 05,CHIM & BIOCHIM PHARMACOL & TOXICOL LAB,CNRS,URA 400,F-75270 PARIS 06,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 20期

关键词：

D O I：

10.1039/c39910001487

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cycloalkanes were oxidized by O2 itself under mild conditions (22-degrees-C; 200 Torr of O2) in the presence of catalytic amounts of a polyhalogenated porphyrin-iron(III)-hydroxo complex irradiated with light of wavelength between 350 and 450 nm; these oxidations occurred without consumption of a reducing agent, selectively transformed cyclohexane into cyclohexanone under appropriate conditions (about 0.2 turnover per min), and did not involve Fe(v) = O active species but, more probably, iron-alkylperoxo intermediates.

引用

页码：1487 / 1489

页数：3

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