ZEOLITE ENCAPSULATED COBALT(II) AND COPPER(II) PERFLUOROPHTHALOCYANINES - SYNTHESIS AND CHARACTERIZATION

被引：126

作者：

BALKUS, KJ ^{[1
]}

GABRIELOV, AG ^{[1
]}

BELL, SL ^{[1
]}

BEDIOUI, F ^{[1
]}

ROUE, L ^{[1
]}

DEVYNCK, J ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM PARIS,ELECTROCHIM ANALYT & APPL LAB,CNRS,URA 216,F-75231 PARIS 05,FRANCE

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 01期

关键词：

D O I：

10.1021/ic00079a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthetic faujasite type zeolites have been modified with cobalt(II) and copper(II) hexadecafluorophthalocyanines (MF(16)Pc) by synthesizing zeolite NaX around the MF(16)Pc complexes and by the template synthesis of the complexes inside NaY zeolites ion exchanged with Co2+ and Cu2+. Mid FT-IR and UV-vis spectroscopy as well as X-ray powder diffraction and elemental analysis provide evidence for the encapsulation of the MF(16)Pc complexes inside the zeolites. The redox properties of the intrazeolite metal complexes were investigated by cyclic voltammetry. Site isolation of these complexes inside the zeolite has resulted in electrochemical data for Co(II)/Co(I) and Cu(II)/Cu(I) redox processes not observed in solution.

引用

页码：67 / 72

页数：6

共 47 条

[1] EFFECTS OF SUPPORTING ELECTROLYTE AND ZEOLITE CO-CATIONS ON THE ELECTROCHEMICAL RESPONSE OF ZEOLITE-MODIFIED ELECTRODES
BAKER, MD
SENARATNE, C
ZHANG, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1992, 88 (21): : 3187 - 3192
[2] THE ENCAPSULATION OF RH(III) PHTHALOCYANINES IN ZEOLITE-X AND ZEOLITE-Y
BALKUS, KJ
WELCH, AA
GNADE, BE
[J]. JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1991, 10 (01): : 141 - 151
[3] APPLICATION OF DIFFERENTIAL SCANNING CALORIMETRY IN THE STUDY OF INTRAZEOLITE METALLOPHTHALOCYANINES
BALKUS, KJ
FERRARIS, JP
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (21) : 8019 - 8020
[4] BALKUS KJ, 1992, Patent No. 5167942
[5] ELECTROCHEMICAL-BEHAVIOR OF ZEOLITE-ENCAPSULATED COBALT PHTHALOCYANINE COMPLEX IN DMSO AND DMF SOLUTIONS
BEDIOUI, F
DEBOYSSON, E
DEVYNCK, J
BALKUS, KJ
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 315 (1-2): : 313 - 318
[6] ELECTROCHEMISTRY OF ZEOLITE-ENCAPSULATED COBALT SALEN COMPLEXES IN ACETONITRILE AND DIMETHYL-SULFOXIDE SOLUTIONS
BEDIOUI, F
DEBOYSSON, E
DEVYNCK, J
BALKUS, KJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (24): : 3831 - 3834
[7] BEDIOUI F, UNPUB J ELECTROANAL
[8] POLYFLUOROARENES .14. SYNTHESIS OF HALOGENOPHTHALOCYANINES
BIRCHALL, JM
HASZELDI.RN
MORLEY, JO
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1970, (19): : 2667 - &
[9] ELECTROACTIVE CATIONS AS PROBES WITHIN ZEOLITES - VOLTAMMETRIC BEHAVIOR OF MERCURY(II) WITHIN ZEOLITE-A
CASSIDY, J
BREEN, W
ODONOGHUE, E
LYONS, MEG
[J]. ELECTROCHIMICA ACTA, 1991, 36 (02) : 383 - 384
[10] Chan Y-W., 1988, PREPR PAP AM CHEM SO, V33, P453

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