RELAXATION PHENOMENA AND MORPHOLOGY OF POLYURETHANE BLOCK COPOLYMERS

被引:28
作者
SPATHIS, G
KONTOU, E
KEFALAS, V
APEKIS, L
CHRISTODOULIDES, C
PISSIS, P
OLLIVON, M
QUINQUENET, S
机构
[1] NATL TECH UNIV ATHENS, DEPT PHYS, GR-15773 ATHENS, GREECE
[2] CNRS, ORG MOLEC & MACROMOLEC, ER 286, F-94320 THIAIS, FRANCE
[3] NATL TECH UNIV ATHENS, DEPT THEORET & APPL MECH, GR-15773 ATHENS, GREECE
来源
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS | 1990年 / B29卷 / 01期
关键词
18;
D O I
10.1080/00222349008212334
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Five types of linear segmented polyurethanes based on a low molecular weight polyester, reacted with 4,4’-diphenylmethane diisocyanate (MDI), and extended with 1,4-butanediol (BDO), have been studied by dynamic mechanical analysis (DMA), thermally stimulated depolarization current method (TSDC), and differential scanning calorimetry (DSC). Different types of transitions and relaxations have been detected and related to the structure and morphology of the block copolymers studied. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码:31 / 48
页数:18
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