HETERO-POLAR HOMONUCLEAR METAL-METAL BONDING IN CLUSTERS

被引：37

作者：

JOHN, GR ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 181卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)85744-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The presence of donor metal to metal bonds is reviewed for plynuclear complexes of osmium. The general nature and reactivity of these systems is considered and illusrated by the electrophilic character of the complex Os6(CO)18. The potential importance of this in catalytic reactions involving clusters is considered. © 1979.

引用

页码：143 / 149

页数：7

共 13 条

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[7] STUDIES OF SOME CARBON COMPOUNDS OF TRANSITION METALS .2. STRUCTURE OF MEC-CME.H2FE2(CO)8
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[J]. ACTA CRYSTALLOGRAPHICA, 1961, 14 (02): : 139 - &
[8] REVERSIBLE OPENING OF A TRINUCLEAR HETEROMETAL CLUSTER
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (01): : 76 - 77
[9] KINETICS OF IODIDE ATTACK ON THE CLUSTER OS6(CO)18
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MANN, AL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 171 (01) : C9 - C13
[10] JOHN GR, 1979, J ORGANOMET CHEM, V169, pC9

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