2-ALPHA,4-DIHYDROXY-1,8-CINEOLE - A NEW POSSUM URINARY METABOLITE

被引：25

作者：

CARMAN, RM

RAYNER, AC

机构：

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1994年 / 47卷 / 11期

关键词：

D O I：

10.1071/CH9942087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2 alpha,4-Dihydroxy-1,8-cineole (2a) is present in the urine of brushtail possums fed a diet enhanced with 1,8-cineole (1). Chemical syntheses of this novel metabolite (2a) and its 2 beta-epimer (19a) are described. The n.m.r. spectra of various 1,8- and 1,4-cineoles are reported, and literature assignments for C1 and C4 in the 1,4-cineole series are corrected.

引用

收藏

页码：2087 / 2097

页数：11

相关论文

共 15 条

[1] C-13 NMR-SPECTRA OF MONOTERPENES [J].

BOHLMANN, F ;

ZEISBERG, R ;

KLEIN, E .

ORGANIC MAGNETIC RESONANCE, 1975, 7 (09) :426-432

[2] PREPARATION AND REARRANGEMENT OF GAMMA-TERPINEOL EPOXIDES [J].

BOWMAN, RM ;

CHAMBERS, A ;

JACKSON, WR .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (14) :1296-&

[3] 7-HYDROXY-1,8-CINEOLE AND 7-CINEOLIC ACID - 2 NEW POSSUM URINARY METABOLITES [J].

BULL, SD ;

CARMAN, RM ;

CARRICK, FN ;

KLIKA, KD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (04) :441-447

[4] PARTIALLY RACEMIC COMPOUNDS AS BRUSHTAIL POSSUM URINARY METABOLITES [J].

CARMAN, RM ;

KLIKA, KD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1992, 45 (04) :651-657

[5] THE DIEPOXIDES OF TERPINOLENE [J].

CARMAN, RM ;

RAYNER, AC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (02) :195-202

[6] THE 4 DIEPOXIDES OF (R)-(+)-LIMONENE [J].

CARMAN, RM ;

KLIKA, KD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1991, 44 (12) :1803-1808

[7] THE ISOMERIC 1,3,3-TRIMETHYL-2-OXABICYCLO[2.2.2]OCTAN-6-OLS (2-HYDROXY-1,8-CINEOLES) [J].

CARMAN, RM ;

FLETCHER, MT .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (05) :1117-1122

[8] 2,9-DIHYDROXY-1,8-CINEOLE AND 2,10-DIHYDROXY-1,8-CINEOLE - 2 NEW POSSUM URINARY METABOLITES [J].

CARMAN, RM ;

GARNER, AC ;

KLIKA, KD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (08) :1509-1521

[9] NMR ASSIGNMENTS FOR SOME 2-SUBSTITUTED 2,6,6-TRIMETHYL-7-OXA-BICYCLO[3.2.1]OCTANES (DIHYDROPINOLS) [J].

CARMAN, RM ;

FLETCHER, MT ;

LAMBERT, LK .

MAGNETIC RESONANCE IN CHEMISTRY, 1988, 26 (03) :271-272

[10] HALOGENATED TERPENOIDS .27. DIBROMO EPOXY DERIVATIVES OF (R)-(+)-LIMONENE [J].

CARMAN, RM ;

GARNER, AC ;

KLIKA, KD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (02) :233-238