SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMISTRY OF COPPER(II), NICKEL(II), COBALT(II) AND ZINC(II) COMPLEXES OF A BINUCLEATING LIGAND WITH [N2S]2O DONORS

被引：8

作者：

ADHIKARY, B ^{[1
]}

NANDA, KK ^{[1
]}

DAS, R ^{[1
]}

MANDAL, SK ^{[1
]}

NAG, K ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

POLYHEDRON | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1016/S0277-5387(00)83180-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A heptadentate ligand (H3L) with a phenoxo group bridging two metal centres has been synthesized by reacting 4-methyl-2,6-diformylphenol with methyl 2-((2-aminoethyl)amino)cyclopent-1-enedithiocarboxylate. Mono- and binuclear complexes of copper(II), nickel(II), cobalt(II) and zinc(II) have been synthesized and characterized by their UV-vis, IR, H-1 and C-13 NMR and EPR spectra. The electrochemistry of the complexes has been studied and the factors affecting electron-transfer reactions of the binuclear complexes vis-a-vis corresponding mononuclear complexes have been examined.

引用

页码：347 / 353

页数：7