Q-SIZED CDS - SYNTHESIS, CHARACTERIZATION, AND EFFICIENCY OF PHOTOINITIATION OF POLYMERIZATION OF SEVERAL VINYLIC MONOMERS

Q-sized CdS semiconductors have been synthesized in several nonaqueous solvents without the use of added stabilizers. The effects of solvent viscosity and dielectric strength, concentration of excess cadmium ions, temperature, and stirring upon the colloids' absorption spectra have been examined. In addition, efficiency of photoinitiation of polymerization of several vinylic monomers has been examined using both bulk and quantum-sized CdS, ZnO, and TiO2. The Q-sized semiconductors demonstrated significantly higher quantum yields for photopolymerization than their bulk-sized counterparts. A correlation between the reactivity of a monomer toward polymerization and its Alfrey and Price Q and e values was observed. Hole scavenging by the solvent was necessary for efficient polymerization to occur. A correlation between the semiconductor photoinitation efficiency, and the reduction potential of its conduction band electrons was also found. On the basis of these observations, a mechanism of an anionic initiation step followed by free radical chain propagation steps has been proposed.