ENANTIOSELECTIVE SYNTHESIS OF (S)-1-METHYLDODECYL ACETATE, A PHEROMONE OF DROSOPHILA-MULLERI, VIA (-)-SPARTEINE-ASSISTED DEPROTONATION OF 1-DODECANOL

被引:71
作者
HINTZE, F [1 ]
HOPPE, D [1 ]
机构
[1] UNIV KIEL,INST ORGAN CHEM,W-2300 KIEL 1,GERMANY
来源
SYNTHESIS-STUTTGART | 1992年 / 12期
关键词
D O I
10.1055/s-1992-26340
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compound was synthesized with 98 % ee by enantioselective lithiation and methylation of 1-dodecanol, employing a new protection/activation method for primary alcohols, followed by asymmetric deprotonation of the carbamate.
引用
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页码:1216 / 1218
页数:3
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