SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [((ET(2)O)MG)(6)(NPH)(4)BR-4] - A MAGNESIUM-IMIDE CAGE SPECIES DERIVED FROM A DIMAGNESYLAMINE SOLUTION

被引：26

作者：

HASCALL, T ^{[1
]}

OLMSTEAD, MM ^{[1
]}

POWER, PP ^{[1
]}

机构：

[1] LAWRENCE LIVERMORE NATL LAB,DEPT CHEM,DAVIS,CA 95616

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199410001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Grignard compounds and amines were converted into “dimagnesylamines” RN‐(MgX)2 as long ago as 1903. Now for the first time a crystalline compound has been obtained from a PhN(MgBr)2 solution in ether and characterized by X‐ray structure analysis. The title compound has a Mg6N4 adamantanyl framework; each Mg2+ ion is solvated by an ether molecule, and the four Br− ions are located above the four hexagonal faces of the Mg6N4 cage. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1000 / 1001

页数：2

共 6 条

[1] SYNTHESIS AND STRUCTURE OF THE MAGNESIUM IMIDE [(THF)MGNPH](6) [J].

HASCALL, T ;

RUHLANDTSENGE, K ;

POWER, PP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (03) :356-357

[2]

Hascall T., 1994, ANGEW CHEM, V106, P350

[3]

Meunier L, 1903, CR HEBD ACAD SCI, V136, P758

[4] ARYLIMINODIMAGNESIUM REAGENTS .14. REACTIONS WITH NITROBENZENES HAVING ELECTRONEGATIVE ORTHO-SUBSTITUENTS - EFFECTS OF REACTION CONDITIONS ON CONDENSATION, REPLACEMENT, AND SUBSTITUTION [J].

OKUBO, M ;

INATOMI, Y ;

TANIGUCHI, N ;

IMAMURA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (10) :3581-3585

[5]

OLMSTEAD MM, 1992, UNPUB

[6] THE CHEMISTRY OF MAGNESYLAMINES [J].

PETYUNIN, PA .

RUSSIAN CHEMICAL REVIEWS, 1962, 31 (02) :100-107

← 1 →