WAVELENGTH DEPENDENCE OF HCO FORMATION IN THE PHOTOLYSIS OF ACETALDEHYDE

被引：40

作者：

GILL, RJ

ATKINSON, GH

机构：

[1] Department of Chemistry, Syracuse University, Syracuse

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)80214-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The wavelength dependence of HCO(0,0,0) formation in the photodissociation of acetaldehyde was measured using narrow (0.1 nm) bandwidth laser excitation and time-resolved intracavity laser detection (TRILD). A sharp energetic onset at 320 ± 1 nm (89.3 ± 0.3 kcal) for HCO(0,0,0) formation was found. The maximum concentration of HCO(0,0,0) occurs between 100 and 250 μs after excitation depending on the wavelength of excitation. © 1979.

引用

页码：426 / 430

页数：5

共 19 条

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