MOLECULAR-STRUCTURES OF THE BIMETALLIC SULFIDE CLUSTERS CP'2MO2CO2S4(CO)(2), CP'2MO2CO2S3(MU(3)-PPH)(CO)(2), CP'3MO3COS4(CO), AND CP'3MO3FES4(SH)

被引：41

作者：

CURTIS, MD ^{[1
]}

RIAZ, U ^{[1
]}

CURNOW, OJ ^{[1
]}

KAMPF, JW ^{[1
]}

RHEINGOLD, AL ^{[1
]}

HAGGERTY, BS ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 11期

关键词：

D O I：

10.1021/om00011a059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and molecular structures of the clusters Cp'3Mo3CoS4(CO), Cp'3Mo3FeS4(SH), and Cp'2Mo2Co2S3(PPh)(CO) are reported along with the structure of the previously known cluster Cp'2Mo2Co2S4(CO)(2). All these compounds have a tetrahedron of metal atoms at distances corresponding to metal-metal single bonds with mu(3)-S ligands capping the triangular metal faces of the tetrahedron to give an overall cubanelike geometry to the clusters. In Cp'2Mo2Co2S3(PPh)(CO), there is one mu(3)-PPh ligand in addition to three mu(3)-S ligands.

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页码：5337 / 5343

页数：7

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共 55 条

[1] THE SYNTHESIS, STRUCTURES, BONDING AND UNUSUAL REACTIVITY OF SULFIDO OSMIUM CARBONYL CLUSTER COMPOUNDS [J].

ADAMS, RD .

POLYHEDRON, 1985, 4 (12) :2003-2025

[2] FORMATION OF BUTENETHIOLATE BY THE RING-OPENING OF TETRAHYDROTHIOPHENE BY A TRIOSMIUM CLUSTER COMPLEX [J].

ADAMS, RD ;

POMPEO, MP ;

WU, WG ;

YAMAMOTO, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) :8207-8213

[3] HETEROGENEOUS CATALYSIS OF THE HYDRODESULFURIZATION OF THIOPHENES IN PETROLEUM - AN ORGANOMETALLIC PERSPECTIVE OF THE MECHANISM [J].

ANGELICI, RJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) :387-394

[4] EQUILIBRIUM AND KINETIC-STUDIES OF SULFUR-COORDINATED THIOPHENES (TH) IN CP(CO)2RU(ETA-1(S)-TH)+ AND CP(CO)(PPH3)RU(ETA-1(S)-TH)+ - MODELS FOR THIOPHENE ADSORPTION ON HYDRODESULFURIZATION CATALYSTS [J].

BENSON, JW ;

ANGELICI, RJ .

ORGANOMETALLICS, 1993, 12 (03) :680-687

[5] EQUILIBRIUM STUDIES OF THE DISPLACEMENT OF ETA-1(S)-THIOPHENES (TH) FROM CP(CO)(PPH3)RU(ETA-1(S)-TH)+ [J].

BENSON, JW ;

ANGELICI, RJ .

ORGANOMETALLICS, 1992, 11 (02) :922-927

[6] SYNTHESIS AND STRUCTURES OF (I-PRC5H4)2V2S4 AND (C5H5)2V2S2(S2C2(CF3)2) - THE INFLUENCE OF PI-BONDING ON THE GEOMETRY OF THE MU-S2 LIGAND [J].

BOLINGER, CM ;

RAUCHFUSS, TB ;

RHEINGOLD, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (20) :6321-6323

[7] C-S BOND-CLEAVAGE IN TRIS(MU-THIOETHER)DITUNGSTEN(III) COMPLEXES IN REACTIONS WITH ANIONIC NUCLEOPHILES, INCLUDING HYDRIDE - SYNTHESIS AND STRUCTURE OF [PPH4][CL3W(MU-THT)2(MU-S(CH2)4CL)WCL3] AND NA[CL3W(MU-SET2)2(MU-SET)WCL3].3THF [J].

BOORMAN, PM ;

GAO, XL ;

FAIT, JF ;

PARVEZ, M .

INORGANIC CHEMISTRY, 1991, 30 (20) :3886-3893

[8] ORGANOMETALLIC OXIDES AND SULFIDES - PREPARATION OF [(ETA-C5H5)TI]5(MU-3-S)6, [(ETA-C5H5)TI]5(MU-3-S)5(MU-3-S2)(MU-4-O), AND (ETA-C5H5)2TI(SH)(MU-O)TI(ETA-C5H5)(MU-S)2-TI(ETA-C5H5)2 BY REDUCTIVE AGGREGATION OF (ETA-C5H5)2TI(SH)2 WITH ZINC POWDER OR BY OXIDATION OF (ETA-C5H5)2TI(CO)2 WITH H2S IN THE PRESENCE OF WATER [J].

BOTTOMLEY, F ;

DAY, RW .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1992, 70 (05) :1250-1259

[9] INVESTIGATION OF THE FORMATION OF NEW BIMETALLIC CLUSTERS OF THE TYPE (ETA-C5ME5)2M2M'2(MU-3-S)4(CO)2 (M=CR,MO - M'=CO), CONTAINING THE M2M'2S4 CORE [J].

BRUNNER, H ;

WACHTER, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 240 (02) :C41-C44

[10] 2,5-DIMETHYLTHIOPHENE COORDINATION TO 3 METAL CENTERS IN (ETA-4,S-MU-3-2,5-ME2T)(IRCPSTAR)[MO(CO)2CP]2 [J].

CHEN, J ;

ANGELICI, RJ .

ORGANOMETALLICS, 1990, 9 (03) :879-880

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