MOLECULAR-STRUCTURES OF THE BIMETALLIC SULFIDE CLUSTERS CP'2MO2CO2S4(CO)(2), CP'2MO2CO2S3(MU(3)-PPH)(CO)(2), CP'3MO3COS4(CO), AND CP'3MO3FES4(SH)

被引：41

作者：

CURTIS, MD ^{[1
]}

RIAZ, U ^{[1
]}

CURNOW, OJ ^{[1
]}

KAMPF, JW ^{[1
]}

RHEINGOLD, AL ^{[1
]}

HAGGERTY, BS ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 11期

关键词：

D O I：

10.1021/om00011a059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and molecular structures of the clusters Cp'3Mo3CoS4(CO), Cp'3Mo3FeS4(SH), and Cp'2Mo2Co2S3(PPh)(CO) are reported along with the structure of the previously known cluster Cp'2Mo2Co2S4(CO)(2). All these compounds have a tetrahedron of metal atoms at distances corresponding to metal-metal single bonds with mu(3)-S ligands capping the triangular metal faces of the tetrahedron to give an overall cubanelike geometry to the clusters. In Cp'2Mo2Co2S3(PPh)(CO), there is one mu(3)-PPh ligand in addition to three mu(3)-S ligands.

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页码：5337 / 5343

页数：7

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