ENANTIOSELECTIVE HYDROGENATION OF ACETOPHENONE IN THE PRESENCE OF S-PROLINE

被引：48

作者：

TUNGLER, A ^{[1
]}

TARNAI, T ^{[1
]}

MATHE, T ^{[1
]}

PETRO, J ^{[1
]}

机构：

[1] TECH UNIV BUDAPEST,DEPT ORGAN CHEM TECHNOL,H-1521 BUDAPEST,HUNGARY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 67卷 / 02期

关键词：

Organic Compounds;

D O I：

10.1016/0304-5102(91)85053-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Enantioselective heterogeneous catalytic hydrogenation of acetophenone in the presence of S-proline was investigated. The effect of various catalytically active metals, reaction temperature and amount of catalyst on optical purity was studied. The correlation between optical yield and conversion, concentration of the reactants, different pretreatment methods and additives was also investigated.

引用

页码：277 / 282

页数：6