LOW-TEMPERATURE (144K) XE-129 NMR-STUDIES OF COADSORPTION OF XENON AND CARBON-TETRACHLORIDE IN NAY ZEOLITE

被引:8
作者
CHEUNG, TTP
机构
[1] Phillips Research Center, Phillips Petroleum Company, Bartlesville
关键词
D O I
10.1021/j100192a059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Xe-129 nuclear magnetic resonance (NMR) of xenon coadsorbed in NaY zeolite with carbon tetrachloride at 144 K has been studied as a function of the xenon loading. The NMR spectra reveal two types of Xe-129 resonances corresponding to xenon in supercages with and without CCl4 molecules. The presence Of CCl4 molecules in the supercage suppresses the gas-liquid transition of the xenon sharing the same cage. On the other hand, the gas-liquid transition of xenon in the supercages without CCl4 molecules can influence the distribution of the carbon tetrachloride in the zeolite.
引用
收藏
页码:5505 / 5509
页数:5
相关论文
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[11]  
WEAST R, 1967, HDB CHEM PHYSICS, pD108