A SQUARE-WAVE VOLTAMMETRY IN A CATHODIC STRIPPING MODE

被引：25

作者：

LOVRIC, M ^{[1
]}

PIZETA, I ^{[1
]}

KOMORSKYLOVRIC, S ^{[1
]}

机构：

[1] MIL SCH TECH SCI, YU-41000 ZAGREB, CROATIA

来源：

ELECTROANALYSIS | 1992年 / 4卷 / 03期

关键词：

CATHODIC STRIPPING VOLTAMMETRY; SQUARE-WAVE VOLTAMMETRY;

D O I：

10.1002/elan.1140040311

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A model of cathodic stripping square-wave voltammetry (SWV) of insoluble mercuric salt accumulated at the mercury drop electrode surface is developed. Theoretical relationships between the properties of responses and the parameters of both the redox reaction and the SWV signal are analyzed. Both reversible and quasireversible redox reactions are considered. The nature of quasireversible maximum is discussed. Numerical simulations are compared qualitatively with the SW stripping voltammograms of electrodeposited HgS.

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收藏

页码：327 / 337

页数：11

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