IRIDIUM(I)-CATALYZED ASYMMETRIC HYDROGENATION OF PROCHIRAL IMINES - PROTIC AMINES AS CATALYST IMPROVERS

被引：83

作者：

TANI, K

ONOUCHI, J

YAMAGATA, T

KATAOKA, Y

机构：

来源：

CHEMISTRY LETTERS | 1995年 / 10期

关键词：

D O I：

10.1246/cl.1995.955

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A catalytic system, Ir(I)-BINAP-protic amine, was found to be effective for asymmetric hydrogenation of imines and the highest enantioselectivity of 90% ee has been attained for the hydrogenation of the cyclic imine, 2-phenyl-3,4,5,6-tetrahydropyridine.

引用

页码：955 / 956

页数：2

共 14 条

[11]

Takaya H., 1993, CATALYTIC ASYMMETRIC, P1

[12] SYNTHESIS OF HIGHLY ENANTIOMERICALLY ENRICHED CYCLIC AMINES BY THE CATALYTIC ASYMMETRIC HYDROGENATION OF CYCLIC IMINES [J].