ALLYLIC OXIDATION OF OLEFINS CATALYZED BY COBALT CHLORIDE - THE BENEFICIAL EFFECT OF N-METHYLPYRROLIDINONE

被引：21

作者：

ALPER, H

HARUSTIAK, M

机构：

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 84卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ALLYLIC OXIDATION; COBALT CHLORIDE; OLEFINS; VANADIUM;

D O I：

10.1016/0304-5102(93)80087-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cobalt chloride in diglyme is a useful catalyst for the allylic oxidation of cyclohexene, affording 2-cyclohexen-1-ol as the major product and 2-cyclohexen-1-one as the by-product. The ketone is the predominant product when the reaction is effected in the presence of N-methylpyrrolidinone. Vanadium compounds [VO (acac)2, C5H5V(CO)4] are also effective catalysts for the latter reaction.

引用

页码：87 / 92

页数：6

共 7 条

[1] PALLADIUM-CATALYZED ALLYLIC OXIDATION OF CYCLOHEXENES USING MOLECULAR-OXYGEN AS OXIDANT [J].