TRANS-DICHLOROOXO(2-PROPOXIDO)BIS(TRIPHENYLPHOSPHINE)RHENIUM(V)

被引：27

作者：

ABRAM, S

ABRAM, U

SCHULZLANG, E

STRAHLE, J

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194013314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound crystallizes with discrete [ReOCl2(C3H7O)(C18H15P)(2)] units. The coordination sphere of the metal atom is approximately octahedral with the bulky phosphine ligands trans with respect to each other. The O=Re-O unit is nearly linear with an angle of 174.25(9)degrees, Both Re-Cl bond lengths, as well as both Re-P lengths, are equal within their standard deviations.

引用

页码：1078 / 1080

页数：3

共 9 条

[1] RHENIUM(V) OXIDE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF THE COMPOUNDS TRANS-ETEI2O(OET)(PPH3)2,TRANS-MEEI2O(OME)(PPH3)2 AND OF THEIR HYDROLYSIS DERIVATIVE REIO2(PPH3)2 [J].