MOLECULAR-HYDROGEN, MOLECULAR-NITROGEN AND MONOHYDRIDE DERIVATIVES OF THE STRUCTURALLY CHARACTERIZED DICHLORO(O-DIPHENYLPHOSPHINO-N,N-DIMETHYLANILINE)[TRIS(P-TOLYL)PHOSPHINE]RUTHENIUM(II) COMPLEX

被引：41

作者：

MUDALIGE, DC ^{[1
]}

RETTIG, SJ ^{[1
]}

JAMES, BR ^{[1
]}

CULLEN, WR ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 10期

关键词：

D O I：

10.1039/c39930000830

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystallographically characterised, five-coordinate complex [RuCl2(o-diphenylphosphino-N,N-dimethylaniline){P(p-tolyl)3}] reversibly binds H-2 and N2 to form eta2-H-2 and sigma-N2 species, respectively; the former reacts with base to generate the chloro(hydrido) derivative.

引用

页码：830 / 832

页数：3

共 16 条

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