HIGHLY ENANTIOSELECTIVE OXIDATION OF FERROCENYL SULFIDES

被引：44

作者：

DITER, P ^{[1
]}

SAMUEL, O ^{[1
]}

TAUDIEN, S ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,SYNTHESE ASYMETRIQUE LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 04期

关键词：

D O I：

10.1016/0957-4166(94)80015-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidation of aryl or alkyl ferrocenyl sulfides by cumene hydroperoxide was investigated in presence of chiral titanium complexes. It was found that the preparation of the combination Ti((OPr)-Pr-i)(4) / DET / H2O = 1 : 2 : 1 is very sensitive to time and temperature. In suitable conditions some aryl ferrocenyl sulfoxides almost enantiomerically pure (> 99% ee) could be produced.

引用

页码：549 / 552

页数：4

共 18 条

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