REMOTE ASYMMETRIC INDUCTION IN REACTIONS BETWEEN 4-BENZYLOXYPENT-2-ENYL(TRIBUTYL)STANNANE AND 5-BENZYLOXYPENT-2-ENYL(TRIBUTYL)STANNANE AND CHIRAL IMINES PREPARED FROM BUTYL GLYOXYLATE

被引：48

作者：

HALLETT, DJ ^{[1
]}

THOMAS, EJ ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transmetallation of 4- and 5-benzyloxypent-2-enyl(tributyl)stannanes 13 and 18 with tin(IV) chloride generates intermediate allyltin trichlorides which react with imines 9 and ent-9, prepared from butyl glyoxylate and either (R)- or (S)-1-phenylethylamine, with effective 1,5-asymmetric induction.

引用

页码：657 / 658

页数：2

共 17 条

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