NITRIC-ACID REACTION OF CYCLOHEXANOL TO ADIPIC ACID

被引：41

作者：

CASTELLAN, A ^{[1
]}

BART, JCJ ^{[1
]}

CAVALLARO, S ^{[1
]}

机构：

[1] UNIV MESSINA,DIPARTIMENTO CHIM IND,I-98010 ST AGATA,ITALY

来源：

CATALYSIS TODAY | 1991年 / 9卷 / 03期

关键词：

D O I：

10.1016/0920-5861(91)80050-J

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The reaction chemistry of the oxidation of cyclohexanol to adipic acid under the influence of nitric acid has been critically reviewed. With the traditional process maximum selectivity towards adipic acid is reached at a high degree of HNO3 consumption. Only under particular reaction conditions can the nitric acid consumption be reduced without affecting the selectivity; certain conditions even lead to improved selectivity.

引用

页码：255 / 283

页数：29

共 64 条

[51] TAVERNIER D, 1977, B SOC CHIM BELG, V86, P273
[52] TOPCHIEV AV, 1959, NITRATION HYDROCARBO, P87
[53] TRUBNIKO.VI, 1969, DOKL AKAD NAUK SSSR+, V184, P871
[54] TRUBNIKOVA VI, 1970, KHIM PROMST MOSCOW, V46, P12
[55] TRUBNIKOVA VI, 1974, ZH PRIKL KHIM, V47, P2272
[56] VANASSELT WJ, 1963, RECL TRAV CHIM PAY B, V82, P51
[57] VANASSELT WJ, 1963, RECL TRAV CHIM PAY B, V82, P429
[58] VANASSELT WJ, 1963, RECL TRAV CHIM PAY B, V82, P438
[59] VESELCHAKOVA TL, 1971, KHIM PROM, V47, P893
[60] WHITE JO, 1965, Patent No. 3170952

← 1 2 3 4 5 6 7 →