BIOMIMETIC SYNTHESIS OF THEONELLIN ISOCYANIDE

被引：28

作者：

ICHIKAWA, Y ^{[1
]}

机构：

[1] MIE UNIV, FAC EDUC, TSU, MIE 514, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 16期

关键词：

D O I：

10.1039/p19920002135

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A marine sesquiterpene of the theonellin class has been synthesized for the first time. Direct amination of the theonelline carbon framework 2 in a biomimetic fashion, a crucial step, was achieved by employing a triflic acid-promoted Ritter-type reaction at low temperature (-78-degrees-C).

引用

页码：2135 / 2139

页数：5