THE C-1S SHAKEUP SPECTRA OF BUCKMINSTERFULLERENE, ACENAPHTHYLENE, AND NAPHTHALENE, STUDIED BY HIGH-RESOLUTION X-RAY PHOTOELECTRON-SPECTROSCOPY AND QUANTUM-MECHANICAL CALCULATIONS

被引：37

作者：

ENKVIST, C

LUNELL, S

SJOGREN, B

BRUHWILER, PA

SVENSSON, S

机构：

[1] LINKOPING UNIV,DEPT PHYS,S-58183 LINKOPING,SWEDEN

[2] UNIV UPPSALA,DEPT PHYS,S-75121 UPPSALA,SWEDEN

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 15期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1063/1.470414

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The C-1s core photoelectron shakeup spectrum of fullerene has been studied experimentally and theoretically, as well as the corresponding spectra of the smaller model compounds acenaphthylene and naphthalene. It is found that many of the shakeup excitations of C-60 Can be classified in terms of excitations found in the model compounds. A population analysis of the orbitals involved reveals a systematic behavior, enabling a generalization to extended aromatic systems and to an infinite graphite layer. (C) 1995 American Institute of Physics.

引用

页码：6333 / 6342

页数：10

共 34 条

[1] CHARACTERIZATION OF THE SOLUBLE ALL-CARBON MOLECULES C60 AND C70 [J].

AJIE, H ;

ALVAREZ, MM ;

ANZ, SJ ;

BECK, RD ;

DIEDERICH, F ;

FOSTIROPOULOS, K ;

HUFFMAN, DR ;

KRATSCHMER, W ;

RUBIN, Y ;

SCHRIVER, KE ;

SENSHARMA, D ;

WHETTEN, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8630-8633

[2] INTERMEDIATE NEGLECT OF DIFFERENTIAL OVERLAP THEORY FOR TRANSITION-METAL COMPLEXES - FE, CO AND CU CHLORIDES [J].

BACON, AD ;

ZERNER, MC .

THEORETICA CHIMICA ACTA, 1979, 53 (01) :21-54

[3] THEORETICAL MODELS FOR INTERPRETATION OF ESCA SPECTRA [J].

BASCH, H .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1974, 5 (NOV-D) :463-500

[4] C-60 AND C-70 FULLERENES AND POTASSIUM FULLERIDES [J].

BENNING, PJ ;

POIRIER, DM ;

OHNO, TR ;

CHEN, Y ;

JOST, MB ;

STEPNIAK, F ;

KROLL, GH ;

WEAVER, JH ;

FURE, J ;

SMALLEY, RE .

PHYSICAL REVIEW B, 1992, 45 (12) :6899-6913

[5]

BRUHWILER PA, 1992, CHEM PHYS LETT, V193, P311, DOI 10.1016/0009-2614(92)85635-N

[6] VIBRATIONAL PROPERTIES OF XE-FULLERENE ADDUCTS - A MOLECULAR-DYNAMICS APPROACH [J].

CARDINI, G ;

PROCACCI, P ;

SALVI, PR ;

SCHETTINO, V .

CHEMICAL PHYSICS LETTERS, 1992, 200 (1-2) :39-45

[7] ELECTRONIC STATES AND PHASES OF KXC60 FROM PHOTOEMISSION AND X-RAY ABSORPTION-SPECTROSCOPY [J].

CHEN, CT ;

TJENG, LH ;

RUDOLF, P ;

MEIGS, G ;

ROWE, JE ;

CHEN, J ;

MCCAULEY, JP ;

SMITH, AB ;

MCGHIE, AR ;

ROMANOW, WJ ;

PLUMMER, EW .

NATURE, 1991, 352 (6336) :603-605

[8] C(1S) SHAKEUP SPECTRUM OF C-60 - GLOBAL CHARGE-TRANSFER SATELLITES AND THEIR RELATION TO THE X-RAY THRESHOLD SINGULARITIES IN MACROSCOPIC SYSTEMS [J].

ENKVIST, C ;

LUNELL, S ;

SJOGREN, B ;

SVENSSON, S ;

BRUHWILER, PA ;

NILSSON, A ;

MAXWELL, AJ ;

MARTENSSON, N .

PHYSICAL REVIEW B, 1993, 48 (19) :14629-14637

[9] DYNAMIC EFFECTS IN VUV-SPECTROSCOPY AND XUV-SPECTROSCOPY OF ORGANIC MOLECULAR-SOLIDS [J].

FREUND, HJ ;

BIGELOW, RW .

PHYSICA SCRIPTA, 1987, T17 :50-63

[10] EXPERIMENTAL-EVIDENCE FOR 400-MEV VALENCE-BAND DISPERSION IN SOLID C-60 [J].

GENSTERBLUM, G ;

PIREAUX, JJ ;

THIRY, PA ;

CAUDANO, R ;

BUSLAPS, T ;

JOHNSON, RL ;

LELAY, G ;

ARISTOV, V ;

GUNTHER, R ;

TALEBIBRAHIMI, A ;

INDLEKOFER, G ;

PETROFF, Y .

PHYSICAL REVIEW B, 1993, 48 (19) :14756-14759

← 1 2 3 4 →