ONE-ELECTRON OXIDATION OF [FE2(ETA-C5H5)2(MU-CO)2(MU-PH2PN(ET)PPH2)] BY 7,7,8,8-TETRACYANO-PARA-QUINODIMETHANE - FORMATION OF A CHARGE-TRANSFER SALT WITH A NOVEL SOLID-STATE STOICHIOMETRY AND STRUCTURE

被引：13

作者：

BELL, SE ^{[1
]}

FIELD, JS ^{[1
]}

HAINES, RJ ^{[1
]}

机构：

[1] UNIV NATAL,DEPT CHEM,MET CLUSTER CHEM UNIT,POB 375,PIETERMARITZBURG 3200,SOUTH AFRICA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [Fe2(eta-C5H5)2(mu-CO)2{mu-Ph2PN(Et)PPh2}] with 7,7,8,8-tetracyano-p-quinodimethane, TCNQ, affords, on crystallization from acetonitrile, a charge-transfer salt, [Fe2(eta-C5H5)2(mu-CO)2{mu-Ph2PN(Et)PPh2}]2(TCNQ)3.2MeCN, with a novel 2:3 stoichiometry; the cations and anions in this species are distributed in segregated stacks, the TCNQ anions packing as trimers along the stack with an intratrimer separation of 3.24(1) angstrom and an intertrimer separation of 3.39(1) angstrom.

引用

页码：489 / 491

页数：3

共 15 条

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