THE PREPARATION AND CHARACTERIZATION OF MONOMERIC LANTHANIDE TETRAPHENYLPORPHYRIN CRYSTALS, [LN(TPP)ACAC-CENTER-DOT-3TCB-CENTER-DOT-8H(2)O] (LN=GD, SM)

被引：11

作者：

JIANG, JZ ^{[1
]}

WEI, LL ^{[1
]}

GAO, PL ^{[1
]}

GU, ZN ^{[1
]}

MACHIDA, KI ^{[1
]}

ADACHI, GY ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,OSAKA 565,JAPAN

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1995年 / 225卷 / 1-2期

关键词：

X-RAY CRYSTALLOGRAPHY; MONOMERIC LANTHANIDE TETRAPHENYLPORPHYRIN CRYSTALS; METALLOPORPHYRINS;

D O I：

10.1016/0925-8388(94)07040-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Crystals of tetraphenylporphyrinato lanthanoid(III) complexes, [Ln(tpp)acac . 3TCB . 8H(2)O] (Ln=Gd, Sm), were prep ared and isolated by direct crystallization of the reaction mixture from solution of toluene:TCB (10:1). Its monomeric composition was characterized on the basis of UV-vis, magnetic circular dichroism (MCD), IR, Raman, H-1 NMR spectra and elemental analysis. Single-crystal lattice parameters were obtained by X-ray crystallography of triclinic [Gd(tpp)acac . 8H(2)O . 3TCB], a = 19.72 Angstrom, b=21.62 Angstrom, c=23.15 Angstrom, alpha=69.64 degrees, beta=81.52 degrees, gamma=83.06 degrees, and V=9048 Angstrom(3).

引用

页码：363 / 366

页数：4

共 10 条

[1]

ADLER AD, 1971, ANN NY ACAD SCI, V207, P7

[2]

ARNOLD DP, 1992, INORG CHIM ACTA, V193, P27

[3] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF LUTETIUM(III) PHTHALOCYANINE DERIVATIVES - LUPC2.CH2CL2 AND [LUPC(OAC)(H2O)2].H2O.2CH3OH [J].