PREPARATION AND MAGNETIC-PROPERTIES OF AL(PF3)(2)

被引：1

作者：

HOWARD, JA ^{[1
]}

JONES, R ^{[1
]}

TOMIETTO, M ^{[1
]}

JOLY, HA ^{[1
]}

机构：

[1] LAURENTIAN UNIV,DEPT CHEM & BIOCHEM,SUDBURY,ON P3E 2C6,CANADA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 11期

关键词：

D O I：

10.1021/ic00115a043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Al(PF3)(2) is produced by reaction of ground-state Al atoms with PF3 in an adamantane matrix at 77 K in a rotating cryostat. This new Al(0) complex has the magnetic parameters a(Al)(1) = 87 MHz, a(p)(2)= 160 MHz a(F)(6) = MHz, and g = 2.0040, values that are consistent with a(2)B(1) ground-state in C-2v symmetry.

引用

页码：3097 / 3098

页数：2

共 18 条

[1]

BENNETT JE, 1970, ADV PHYS ORG CHEM, V8, P1

[2] CRYOCHEMICAL STUDIES .6. ELECTRON-SPIN-RESONANCE STUDIES OF THE REACTION OF GROUP-1B METAL ATOMS WITH ARENES AT 77 K IN A ROTATING CRYOSTAT [J].

BUCK, AJ ;

MILE, B ;

HOWARD, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (11) :3381-3387

[3] THE NATURE OF THE CO-ORDINATE LINK .4. COMPLEX FORMATION BY PHOSPHORUS TRIFLUORIDE [J].

CHATT, J ;

WILLIAMS, AA .

JOURNAL OF THE CHEMICAL SOCIETY, 1951, (NOV) :3061-3067

[4] THE INFRARED-SPECTRUM OF DICARBONYL ALUMINIUM(O), AL(CO)2 [J].

CHENIER, JHB ;

HAMPSON, CA ;

HOWARD, JA ;

MILE, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) :730-732

[5] ELECTRON-PARAMAGNETIC-RES SPECTRA OF AL(CO)2 IN HYDROCARBON MATRICES [J].

CHENIER, JHB ;

HAMPSON, CA ;

HOWARD, JA ;

MILE, B ;

SUTCLIFFE, R .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (08) :1524-1528

[6] ESR-SPECTRA OF PF2 AND SF3 RADICALS [J].

COLUSSI, AJ ;

MORTON, JR ;

PRESTON, KF ;

FESSENDEN, RW .

JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (03) :1247-1248

[7] INFRARED SPECTROSCOPIC EVIDENCE FOR ALUMINUM DICARBONYL [J].

HINCHCLIFFE, AJ ;

OGDEN, JS ;

OSWALD, DD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (06) :338-+

[8] EPR-SPECTRUM OF CUPF3 [J].

HISTED, M ;

HOWARD, JA ;

JONES, R ;

TOMIETTO, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (03) :1141-1143

[9] EPR-SPECTRUM OF AGPF3 [J].

HISTED, M ;

HOWARD, JA ;

JONES, R ;

TOMIETTO, M ;

JOLY, HA .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (03) :1144-1146

[10] ELECTRON-SPIN RESONANCE-SPECTRA OF THE ALUMINUM TRIMER IN HYDROCARBON MATRICES - A QUARTET 4A2 STATE [J].

HOWARD, JA ;

SUTCLIFFE, R ;

TSE, JS ;

DAHMANE, H ;

MILE, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (17) :3595-3598

← 1 2 →