A SIMS STUDY OF NICKEL DEPOSITION ON TIO2(100) - INFLUENCE OF THE STOICHIOMETRY OF THE SUPPORT

被引:15
作者
BOURGEOIS, S
JOMARD, F
PERDEREAU, M
机构
[1] Faculté des Sciences Mirande, Laboratoire de Recherches sur la Réactivité des Solides, 21004 Dijon Cedex
关键词
D O I
10.1016/0039-6028(91)90844-I
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nickel deposition on a clean TiO2(100) surface was studied mainly by secondary ion mass spectrometry (SIMS). Different kinds of supports exhibiting a more or less high deviation from stoichiometry were used. For a quasi-stoichiometric support a layer-by-layer growth of 2 or 3 nickel layers is obtained followed by a nucleation stage. For a non-stoichiometric support nickel is found to diffuse into the bulk TiO2 even at room temperature. The influence of temperature on this diffusion was also studied.
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页码:194 / 198
页数:5
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